The application potential of metal-organic frameworks was first discovered around 20 years ago, and almost 100,000 such hybrid porous materials have since been identified. There are great hopes for technical applications, especially for flexible MOFs. As shock absorbers, for example, they could react to sudden high pressure by closing their pores and losing volume, i.e. deforming plastically. Or they could separate chemical substances from each other like a sponge by absorbing them into their pores and releasing them again under pressure. “This would require much less energy than the usual distillation process,” explains Rochus Schmid. However, only a few such flexible MOFs have been identified to date.
MOFs under pressure
In order to get to the bottom of the underlying mechanisms within such materials, the Munich team has carried out a more detailed experimental analysis of an already widely known MOF. To this end, the researchers subjected it to uniform pressure from all sides, while observing what goes on inside using X-ray structure analysis.
“We wanted to know how the material behaves under pressure and which chemical factors are the driving force behind the phase transitions between the open-pored and closed-pore state,” says Gregor Kieslich. The experiment showed that the closed-pore form is not stable; under pressure the system loses its crystalline order, in short: it breaks down.
This is not the case with a variant of the same basic structure: if the team attached flexible side chains of carbon atoms to the organic connecting pieces of the MOF that protrude into the pores, the material remained intact when compressed and resumed its original shape when the pressure decreased. The carbon arms turned the non-flexible material into a flexible MOF.
The secret of phase transformation
The Bochum team investigated the underlying principles using computer chemistry and molecular dynamics simulations. “We have shown that the secret lies in the degrees of freedom of the side chains, the so-called entropy,” outlines Rochus Schmid. “Every system in nature strives for the greatest possible entropy, to put it simply, the greatest possible number of degrees of freedom to distribute the energy of the system.”
“The large number of possible arrangements of the carbon arms in the pores ensures that the open-pored structure of the MOF is entropically stabilized,” Schmid continues. “This facilitates a phase transformation from the open-pored to the closed-pore structure and back again, instead of breaking down when the pores are squeezed together as would be the case without the carbon arms.” In order to calculate such a large system comprised of many atoms and to search for the many possible configurations of the arms in the pores, the team developed a precise and numerically efficient theoretical model for the simulation.
The key result of the study is the identification of another chemical option to control and modify the macroscopic response behavior of an intelligent material by a thermodynamic factor. “Our findings open up novel ways to specifically achieve structural phase transformations in porous MOFs,” concludes Gregor Kieslich.
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More information:
Pia Vervoorts et al. Configurational Entropy Driven High‐Pressure Behavior of a Flexible Metal–Organic Framework (MOF), Angewandte Chemie International Edition (2020). DOI: 10.1002/anie.202011004
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Ruhr-Universitaet-Bochum
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Metal-organic frameworks become flexible (2020, November 17)
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