A team of engineers at the University of Massachusetts Amherst has recently shown that nearly any material can be turned into a device that continuously harvests electricity from humidity in the air. The secret lies in being able to pepper the material with nanopores less than 100 nanometers in diameter. The research appeared in the journal Advanced Materials.
“This is very exciting,” says Xiaomeng Liu, a graduate student in electrical and computer engineering in UMass Amherst’s College of Engineering and the paper’s lead author. “We are opening up a wide door for harvesting clean electricity from thin air.”
“The air contains an enormous amount of electricity,” says Jun Yao, assistant professor of electrical and computer engineering in the College of Engineering at UMass Amherst, and the paper’s senior author. “Think of a cloud, which is nothing more than a mass of water droplets. Each of those droplets contains a charge, and when conditions are right, the cloud can produce a lightning bolt—but we don’t know how to reliably capture electricity from lightning. What we’ve done is to create a human-built, small-scale cloud that produces electricity for us predictably and continuously so that we can harvest it.”
The heart of the man-made cloud depends on what Yao and his colleagues call the “generic Air-gen effect,” and it builds on work that Yao and co-author Derek Lovley, Distinguished Professor of Microbiology at UMass Amherst, had previously completed in 2020 showing that electricity could be continuously harvested from the air using a specialized material made of protein nanowires grown from the bacterium Geobacter sulfurreducens.
“What we realized after making the Geobacter discovery,” says Yao, “is that the ability to generate electricity from the air—what we then called the ‘Air-gen effect’—turns out to be generic: literally any kind of material can harvest electricity from air, as long as it has a certain property.”
That property? “It needs to have holes smaller than 100 nanometers (nm), or less than a thousandth of the width of a human hair.”
This is because of a parameter known as the “mean free path,” the distance a single molecule of a substance, in this case water in the air, travels before it bumps into another single molecule of the same substance. When water molecules are suspended in the air, their mean free path is about 100 nm.
Yao and his colleagues realized that they could design an electricity harvester based around this number. This harvester would be made from a thin layer of material filled with nanopores smaller than 100 nm that would let water molecules pass from the upper to the lower part of the material. But because each pore is so small, the water molecules would easily bump into the pore’s edge as they pass through the thin layer. This means that the upper part of the layer would be bombarded with many more charge-carrying water molecules than the lower part, creating a charge imbalance, like that in a cloud, as the upper part increased its charge relative to the lower part. This would effectually create a battery—one that runs as long as there is any humidity in the air.
“The idea is simple,” says Yao, “but it’s never been discovered before, and it opens all kinds of possibilities.” The harvester could be designed from literally all kinds of material, offering broad choices for cost-effective and environment-adaptable fabrications. “You could imagine harvesters made of one kind of material for rainforest environments, and another for more arid regions.”
And since humidity is ever-present, the harvester would run 24/7, rain or shine, at night and whether or not the wind blows, which solves one of the major problems of technologies like wind or solar, which only work under certain conditions.
Finally, because air humidity diffuses in three-dimensional space and the thickness of the Air-gen device is only a fraction of the width of a human hair, many thousands of them can be stacked on top of each other, efficiently scaling up the amount of energy without increasing the footprint of the device. Such an Air-gen device would be capable of delivering kilowatt-level power for general electrical utility usage.
“Imagine a future world in which clean electricity is available anywhere you go,” says Yao. “The generic Air-gen effect means that this future world can become a reality.”
Xiaomeng Liu et al, Generic Air‐Gen Effect in Nanoporous Materials for Sustainable Energy Harvesting from Air Humidity, Advanced Materials (2023). DOI: 10.1002/adma.202300748. onlinelibrary.wiley.com/doi/10.1002/adma.202300748
University of Massachusetts Amherst
Engineers harvest abundant clean energy from thin air, 24/7 (2023, May 24)